1,3,5-triazine
| 1,3,5-Triazine | |
|---|---|
 |  |
| 1,3,5-Triazine | |
| Another name sym-Triazine s-Triazine Cyanidine Hydrogen cyanide trimer Vedita | |
| Identification information | |
| CAS registration number | 290-87-9  |
| ChemSpider | 8905 |
| ChEBI | CHEBI: 30259 |
| ChEMBL | CHEMBL15698 |
| RTECS number | XY2957000 |
| |
| |
| Characteristic | |
| Chemical formula | C3H3N3 |
| Molar mass | 81.08 g/mol |
| The appearance | White crystal solid |
| Melting point | 81-83 degrees Celsius, 271 K, -36 degrees Fahrenheit |
| Structure | |
| Form of molecules | Plane |
| Electric dipole moment | 0 |
| The risk | |
| The main risk | Water and reaction |
| Associated material | |
| I can put a case, the data without the special mention for normal temperature (25 degrees Celsius), the ordinary pressure (100 kPa). | |
1,3,5-triazine (1,3,5-Triazine) or S-triazine is an organic compound of chemical formula (HCN)3. Having the heteroaromatic ring of the six-membered ring, it is one of some isomers of triazine. S-triazine and the derivative have various application.
Table of contents
Manufacturing method
1,3,5-triazine of the symmetry form is produced by the trimerization of nitriles such as cyan chloride or the cyan imide.
The benzoguanamine (1 phenyl 2 amino substitute) is formed of benzonitrile and dicyandiamide [1]. After [2], reactant being alkyl or allyl amidine and carbon oxychloride [3], and having inserted an N-H group in hydrazide by [4], copper carbenoid by the triazine composition of the pinner, a triazine frame is provided by handling it with ammonium chloride [5].
Applied
S-triazine is equivalent, and, as an organic synthetic reagent, it is used with hydrogen cyanide. Because it is a solid whereas hydrogen cyanide is gas, it is easy to treat triazine more. I let you add formyl radical to an aromatic substrate by the Gattermann reaction [6].
Triazine
N- of triazine and the C-substitute are used industrially. The most common derivative is 2,4,6-thoria Mino-1,3,5-triazine known as melamine. Other important derivatives have 2,4,6-trihydroxy-1,3,5-triazine known as cyanuric acid. As for trichloro-1,3,5-triazine known as cyanuric acid chloride, it is many herbicidal synthetic raw materials such as simazine or the atrazine. Triazine chloride is one of the important fabrics of the reaction dye covalently linking to a cellulosic [7].
In addition, triazine is seen in the pharmaceutical products [8].
Source
- ^ Benzoguanamine J. K. Simons and M. R. Saxton Organic Syntheses Coll. Vol. 4, p.78; Vol. 33, p.13 Article
- ^ A. Pinner, Ber. 23, 2919 (1890)
- ^ Name reactions and reagents in organic synthesis, Bradford P. Mundy, Michael G. Ellerd, Frank G. Favaloro
- ^ Triazines. XIV. The Extension of the Pinner Synthesis of Monohydroxy-s-triazines to the Aliphatic Series. 2,4-Dimethyl-s-triazine1-3 Hansjuergen Schroeder, Christoph Grundmann J. Am. Chem. Soc., 1956, 78 (11), pp 2447–2451 doi: 10.1021/ja01592a028
- ^ Shi, B.; Lewis, W.; Campbell, I. B.; Moody, C. J. Org. Lett., 2009, 3686-3688 doi: 10.1021/ol901502u
- ^ Roswitha M. Böhme, Qun Dang "1,3,5-Triazine" in Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi: 10.1002/047084289X.rt158.pub2
- ^ Horst Tappe, Walter Helmling, Peter Mischke, Karl Rebsamen, Uwe Reiher, Werner Russ, Ludwig Schläfer and Petra Vermehren "Reactive Dyes"in Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH, Weinheim. doi: 10.1002/14356007.a22_651
- ^ Aksenov A. V., Aksenova, I. V. "Use of the ring opening reactions of 1,3,5-triazines in organic synthesis" Chemistry of Heterocyclic Cmpds. 45, pp 130-150 (2009). doi: 10.1007/s10593-009-0243-5
This article is taken from the Japanese Wikipedia 1,3,5-triazine
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