2016년 8월 29일 월요일

Pyroligneous acid

Pyroligneous acid

A thing for the supernatant liquid of the distillation liquid to occur when I performed distillation of wood with the pyroligneous acid (it is stinking and obtains it and comes). As a representative example, pyroligneous acid is made as a by-product at the time of charcoal making. The appearance is a liquid of the 赤褐 - dark brown. Most are water, but organic acid (acetic acid) derived from wood is included and shows subacidity. As other ingredient, aromatic compounds such as alcohols, carbonyl compounds or phenols and franc are included [1]; [2]. The toxic high materials such as formaldehyde or the benzopyrene are included. Is uneven in an ingredient by the condition of raw materials and the distillation [3]; [4] [5].

"The spirit of a tree" who is another name for methanol comes from that I have been ever provided by the distillation of the pyroligneous acid. The phenols arise from the lignin which is an ingredient of the wood mainly.

Table of contents

Wood distillation industry

Business to prepare sodium acetate as a mordant begins with acetic acid provided by the distillation of the pyroligneous acid from about 1820 in the U.K. [6].

Use

The pyroligneous acid was used to prepare acetic acid and methanol, but, as for the source of supply of those chemical substances, was replaced chemical synthesis or the brewing once.

There are pesticidal use or a folk remedy, the use in the public welfare purpose now.

By the liquid smoking that is one of the food processing methods, 燻液 (with the smoked flavor) obtained from the pyroligneous acid is used.

The pyroligneous acid was registered as an antifungal pesticide in the past, but is a lapse pesticide now because registration lapses (a pesticide registration number: 12850, the kind of the pesticide: pyroligneous acid, the name of the pesticide: Izutsuya Matsune pyroligneous acid, an applicant: Izutsuya, a pesticide registration day: on February 28, 1973 an expiration date: February 28, 1979) [7] [8]. According to Professor Naoki Motoyama of the Chiba University Faculty of Horticulture, the ingredient of the pyroligneous acid has unevenness and announces it to Japan environment animal Entomological Society official journal of a scientific society when there was the mutagenic thing damaging the gene of the microbe among them. [9][10], about the sale of the pyroligneous acid, the sale that declared the effect of the pesticide now is prohibited again by the pesticide control method [11]; [12].

I am sold with the following names, but these are not pesticides with pharmaceutical products either, and the efficacy is not recognized now.

  • Pesticidal use
    • Evasion of the animal
    • Pest measures
    • Soil improvement
  • The public welfare
    • Bathing
    • Deodorization
    • Sterilization

Charcoal kiln

The charcoal kiln has white charcoal, soft charcoal and is still a tradition kiln succeeded to in each area. Pyroligneous acid provided in those charcoal kilns is used for the public welfare purposes such as bath articles.

Footnote

  1. Document about the ^ component
  2. ^ Summary of the test result about efficacy, a harmful effect, the safety
  3. ^ Matsui, Matsushita, Kan book, "analysis Miyazaki University department of engineering bulletin, 37 of a preparation and the analysis of the carbonization product of the square stone quality of wood system biomass: vinegar liquid, tar of the cedar bark and the cedar leaf", 57-64 pages of - online versions (the thing that I was carbonized at 400 degrees Celsius, and the sample of the cedar was got as for the pyroligneous acid analyzed in this article)
  4. According to the ^ Matsui and others, four kinds of organic compounds included in more than 1 g in 1 kg of sample of the pyroligneous acid obtained from the cedar include acetic acid, Ase Thor, methanol, pyrocatechol.
  5. Council for ^ agriculture material pesticide subcommittee identification pesticide subcommittee and council for central environment soil pesticide sectional meeting pesticide subcommittee sixth combination meeting distribution document - Ministry of Agriculture, Forestry and Fisheries August 31, 2005 (with the sample that the ingredient cited in with this document prepared it in the range of 80-150 degrees Celsius)
  6. ^ D. C. McClure, Kilkerran Pyroligneous Acid Works 1845 to 1945 - Ayrshire History
  7. ^ List of registration lapse active ingredients - incorporated administrative agency agriculture and forestry fisheries consumption security technique center (FAMIC)
  8. ^ List of registration lapse active ingredients - incorporated administrative agency agriculture and forestry fisheries consumption security technique center (FAMIC)
  9. ^ Osamu Komagata. For Naoki Motoyama "mutagenesis ("http://kandoukon.org/paper/paperlong/volume15issue4.pdf") of the various marketing and homemade pyroligneous acid, bamboo vinegar liquid", "環動昆" Vol. 15 fourth, Japanese environmental animal Entomological Society, 2,004 years, it is 231-238 pages, ISSN 0915-4698.
  10. The specific pesticide which is usable by ^ farming without agricultural chemicals freely, an effect and safety to be called into question
  11. With the ^ Ministry of Agriculture, Forestry and Fisheries / identification pesticide?
  12. It is from Ministry of Agriculture, Forestry and Fisheries production chief of the bureau about the enforcement of the law to revise a part of the ^ pesticide control method for three days on (notice), 14 production 10052nd, 1, Heisei March 1, 5

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