2017년 6월 24일 토요일

Hydrogenation copper

Hydrogenation copper

Hydrogenation copper (すいそかどう, copper hydride, CuH) is copper hydride. The Cu-H combination is weak, and, as for the structure, there is the explosiveness which is instability [1] [2]. Red hydrogenation copper precipitates when I return copper sulfate (II) with phosphinic acid sodium in water solutions. I disintegrate to metal copper and gas hydrogen when I heat deposition. X-rays structure is reported [3]. The material which I added triphenyl phosphine to is called a striker reagent.

Hydrogenation copper
Identification information
CAS registration number 13,517-00-5
PubChem 3335333
ChemSpider 2582262 Check
Characteristic
Chemical formula HCu
Molar mass 64.55 g mol-1
Exact mass 63.937426111 g of mol-1
I can put a case, the data without the special mention for normal temperature (25 degrees Celsius), the ordinary pressure (100 kPa).

Source

  1. ^ Hydrides of the Main-Group Metals: New Variations on an Old Theme Simon Aldridge, Anthony J. Downs Chem. Rev., 2001, 101 (11), pp 3305–3366 doi: 10.1021/cr960151d
  2. ^ Laboratory Methods of Inorganic Chemistry Wilhelm Biltz Heinrich
  3. ^ The crystal structure of copper hydride J. A. Goedkoop and A. F. Andresen Acta Cryst. (1955). 8, 118-119 doi: 10.1107/S0365110X55000480

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