2016년 4월 30일 토요일

2,4,6-avian chlorophenol

2,4,6-avian chlorophenol

2,4,6-avian chlorophenol
2,4,6-Trichlorophenol
Identification information
CAS registration number 88-06-2 Check
ChemSpider 6648 Check
EINECS 604-018-00-5
United Nations number 2020
RTECS number SN1575000
Characteristic
Chemical formula C6H2Cl3OH/C6H3Cl3O
Molar mass 197.45 g/mol
The appearance Solid [2] of the ecru
Smell It smells of phenol [1]
Density 1.675 g/cm3
Melting point

69 degrees Celsius [3]

The boiling point

246 degrees Celsius [3]

Solubility to water 800 mg/l [2]
The risk
R phrase R22, R36, R38, R40, R50, R53
S phrase (S2), S36, S37, S60, S61
Ignition point 99 degrees Celsius [3]
LD-50 LD50 820 mg/kg (rat)
Associated material
Related material Chlorophenol
Dichlorophenol
Trichlorobenzene

I can put a case, the data without the special mention for normal temperature (25 degrees Celsius), the ordinary pressure (100 kPa).

The 2,4,6-avian chlorophenol (British: 2,4,6-Trichlorophenol) is a kind of the organochlorine. There is another name for 2,4,6-TCP and Omar, Dow Ishido 2S. With a solid of the ecru, I hit a phenol smell.

Table of contents

Use

I am used as a sterilizer and a wood preservative, an intermediate of the dye.

In late years the material used as a cork sterilizer changes into 2,4,6-bird chloroanisole by a microbe, and it has it pointed out to cause the bad smell to shift to the wine which I corked, and to be said to be "a cork smell" [4].

Safe

By the heating resolution, I produce the poisonous gases such as chlorine or the hydrogen chloride [1].

Influence on health

In animal experiment with the oral administration for 2 years, outbreak frequency of a malignant lymphoma and leukemia significantly increases to a male rat, and hepatocellular carcinoma and adenoma increase the sex with the mouse together. From this, in the United States of America Environmental Protection Agency, B2, the international cancer research organization evaluate a carcinogenic risk about mixed revelation to polychlorinated phenols and the sodium salt by EPA carcinogenicity evaluation with Group2B [2].

By production grade, polychlorinated dibenzo Para dioxin (en, PCDDs) and polychlorinated dibenzo furan (PCDFs) may be included [5].

Influence on environment

The 96 hours half causing death density of guppy (LC50) 610 μg/l, 96 hours half influence on algal a kind of Selenastrum capricornutum density (EC50) with the findings such as 3,500 μg/l [2]. Because there is rapid degradability, it is thought that the chronic influence on environment is low [1].

Footnote

  1. ^ a b c Material Safety Data Sheet (association of prevention of central work-related accident)
  2. ^ a b c d Environmental risk evaluation Vol. 2 of the chemical substance (PDF)Ministry of the Environment
  3. ^ a b c International Chemical Safety Card
  4. The cause of the cork smell of the ^ wine is reading on August 8, 2012 on mutter -Chem Station, August 5, 2007 of the chemist
  5. ^ 2,4,6-Trichlorophenol. ICSC 1122. IPCS. (Nov 1998). http://www.oit.org/public/english/protection/safework/cis/products/icsc/dtasht/_icsc11/icsc1122.htm November 16, 2007 reading. . 

This article is taken from the Japanese Wikipedia 2,4,6-avian chlorophenol

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