2017년 5월 27일 토요일

Nitrating acid

Nitrating acid

The liquid which mixed strong sulfuric acid and concentrated nitric acid with the nitrating acid (こんさん British: mixed acid) at a volume ratio of 3:1. I am used for the nitration of aromatic compounds. I call even sulfuric acid and a combination except the nitric acid nitrating acid, but nitric acid refers to a mixture of the sulfuric acid integrally.

Reaction mechanism of the nitration

In nitrating acid, ニトロニウムイオン NO2+ of 1 molecule arises from nitric acid 1 molecules and 2 molecules sulfate.

HNO3 + 2H2SO4 → NO2+ + 2HSO4- + H3O+

ニトロニウムイオン which occurred is very strong 求電子剤 and produces a nitro-compound in response to aromatic compounds.

Allied item

This article is taken from the Japanese Wikipedia Nitrating acid

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